{"id":1977,"date":"2015-09-16T12:11:46","date_gmt":"2015-09-16T12:11:46","guid":{"rendered":"http:\/\/hydrogen.wsu.edu\/?page_id=1977"},"modified":"2016-01-06T15:30:54","modified_gmt":"2016-01-06T23:30:54","slug":"hydrogen-source","status":"publish","type":"page","link":"https:\/\/hub.wsu.edu\/ise\/design\/hydrogen-source\/","title":{"rendered":"Hydrogen source"},"content":{"rendered":"<br \/>\n<section id=\"builder-section-1443126847808\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Our Team<\/h2>\n<\/header>\n<p style=\"text-align: center\">\u00a0<a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/IMG_20151016_1358532.jpg\"><img decoding=\"async\" loading=\"lazy\" class=\"alignnone wp-image-3214 size-full\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/IMG_20151016_1358532.jpg\" alt=\"IMG_20151016_135853\" width=\"3645\" height=\"1122\" \/><\/a><\/p>\n<p style=\"text-align: center\">Hello! We are the WSU H2-Refuel Hydrogen Source Team.<br \/>\nTop Row (From left to right): Ryan Brown, Ryan Whitehead, Paul Flerchinger, Zachary Gilvey \u00a0Ryan Whitehead, Derek Johnson<br \/>\nBottom Row: Avery Scott, Bailee DePhelps, Ashley Vu, Daniel Barnes, Ryan Fish, David Lopez-Nava<br \/>\nOur team consists of Junior&#8217;s and Senior&#8217;s in the Mechanical Engineering Department at Washington State University.<\/p>\n<h2 style=\"text-align: center\"><\/h2>\n<blockquote>\n<h2 style=\"text-align: center\">Similar to James Bond, a hydrogen bond is just as difficult to break.<\/h2>\n<h2 style=\"text-align: center\">If you want to be a part of the next generation of fueling, the Hydrogen Source group and the WSU H2Refuel Team can help you get there.<\/h2>\n<p>&nbsp;<\/p>\n<h2>Our Goal<\/h2>\n<\/blockquote>\n<p>Hydrogen is one of the great elements that has the potential to change the transportation as we know it today. To implement this underutilized element, we are using water, methane, and electricity (as specified in the H2Refuel rules) to produce gaseous hydrogen as our product for fueling the future. To do this, we need to create a system that separates hydrogen from water or methane OR utilizes syngas. The two most promising methods currently available include steam methane reforming and electrolysis. Our subsystem is vital\u00a0because we provide the gaseous hydrogen, which will be utilized by all of the other groups to be purified, liquefied, and pressurized to be dispensed into a car. Thus, if our process doesn\u2019t work, the whole system is unable to produce a working product.<\/p>\n<p><b>Fundamentals<\/b><\/p>\n<p>Methane, water, and electricity are the only inputs to the system and the output will yield 99.99% pure gaseous hydrogen and potentially waste gases from methane. In addition, this subsystem should be capable of generating power for some of the other processes and outputting as high of a pressure as possible.<\/p>\n<\/p><\/div>\n<\/section>\n<section id=\"builder-section-1443126868598\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Background<\/h2>\n<\/header>\n<p><strong>Electrolysis:<\/strong><\/p>\n<p><span style=\"font-weight: 400\">Electrolysis of water was revolutionized in the 1800s. In 1902, industrial water electrolysis units were being used and by 1939, the first large plant was utilized. The first pressurized industrial electrolyser was manufactured in 1948. The first solid polymer electrolyte system was built in 1966. The first solid oxide water electrolysis unit was built in 1972. Developed by DuPont and other manufacturers, water electrolysis now utilizes proton exchange membranes that are now usable for water electrolysis units and fuel cells. More info <a href=\"http:\/\/www.cres.gr\/kape\/publications\/papers\/dimosieyseis\/ydrogen\/A%20REVIEW%20ON%20WATER%20ELECTROLYSIS.pdf\">here<\/a>.<\/span><\/p>\n<ul>\n<li><span class=\"s1\">Electricity flows through a positive and negative electrode<\/span><\/li>\n<li>The hydrogen and oxygen ions in the water flow to the oppositely charged electrode where hydrogen and oxygen bubbles float to the surface<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center\"><a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/ELectrolysis-use.png\"><img decoding=\"async\" loading=\"lazy\" class=\"size-medium wp-image-2808 aligncenter\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/ELectrolysis-use-396x563.png\" alt=\"ELectrolysis use\" width=\"396\" height=\"563\" \/><\/a><\/p>\n<p style=\"text-align: center\">Fig 1) Electrolysis Process: How it Works<\/p>\n<p style=\"text-align: left\"><strong>Steam Methane Reformer:<\/strong><\/p>\n<p><span style=\"font-weight: 400\">Steam Methane Reforming is a common industrial process, used in the production of ammonia as well as hydrogen gas. As such, it has been extensively researched, particularly in the large scale applications that occur in chemical factories. The performance of steam methane reforming systems at smaller, modular scales is a more recent topic of interest. The reforming process utilizes high temperatures over catalysts, often nickel alloys, to react methane and steam. The product of the reforming is syngas, a mixture of hydrogen, carbon monoxide and dioxide, and some residual methane. This syngas is then further treated in a secondary shift reaction with more steam, which converts the remaining carbon monoxide into carbon dioxide and more hydrogen. This process has a high theoretical efficiency, on the order of 90%. However, this efficiency is not attainable at small scales, where typical efficiencies are between 60 and 80%, assuming that waste heat is reclaimed effectively. It has the potential to be an inexpensive alternative for the production of hydrogen in our fueling station. A diagram of the basic process flow is below. More info <a href=\"http:\/\/www.h2alliance.com\/pdf\/ie3002843.pdf\">here<\/a>.<\/span><\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-2809 size-full\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/SMR-use.jpg\" alt=\"SMR use\" width=\"945\" height=\"337\" \/><\/p>\n<p style=\"text-align: center\">Fig 2) Steam Methane Reforming Process: How it Works<\/p>\n<ul>\n<li style=\"text-align: left\">SMR uses High Temperatures and catalysts to force two chemical reactions:\n<ul>\n<li style=\"text-align: left\">CH4+2H2O =&gt; CO2+4H2<\/li>\n<li style=\"text-align: left\">CH4+H2O =&gt; CO+3H2<\/li>\n<\/ul>\n<\/li>\n<li style=\"text-align: left\">A second phase at lower temperatures converts the CO into CO2\n<ul>\n<li style=\"text-align: left\">CO+H2O =&gt; CO2+H2<\/li>\n<\/ul>\n<\/li>\n<li style=\"text-align: left\">The carbon dioxide can be separated out using pressure swing adsorption, typically leaving very pure hydrogen.<\/li>\n<li style=\"text-align: left\">The inputs, methane and water, are usable as is.<\/li>\n<li style=\"text-align: left\">Fairly low energy consumption and operating cost.<\/li>\n<\/ul><\/div>\n<\/section>\n<section id=\"builder-section-1443126899972\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Design Specification<\/h2>\n<\/header>\n<p>We can objectively rank our different design alternatives by using a system known as the House of Quality. It is similar to the chart below, except the engineering characteristics are weighted according to their importance.<\/p>\n<p>A House of Quality ranks the relationship between system requirements and design alternatives. As we have researched and developed our system these relationships helped us optimize our design. The vertical axis consists of system requirements and measurable qualities that are most relevant to our design. The horizontal axis displays design alternatives. From this chart we are able to compare how each design alternative relates to the system requirement.\u00a0This allows us to generate an objective \u201cscore\u201d for each design concept, which aids in the selection process.<\/p>\n<p><span style=\"font-weight: 400\">Our team encountered several problems while using the HOQ to determine our design. For instance, we had identified our most important factors to be the amount of space our design would take, cost, and the hydrogen output amount. We found several options that were available, but all had their pros and cons that needed to be considered. For instance, an SMR machine would produce the ideal hydrogen output, but took up far too much space in the container. The HOQ proved to us that our two best options were a self built SMR system or electrolysis. Finally, after further research on commercially available electrolysis machines, our HOQ showed that electrolysis would be our best option given our requirements.\u00a0<\/span><\/p>\n<p style=\"text-align: center\">To view our full HOQ, click <a href=\"https:\/\/docs.google.com\/document\/d\/11KcIPs_Ekjl0wE7rpE7v-FO3d957rvrahuQpaKKx5Lo\/edit\">here<\/a><\/p>\n<p style=\"text-align: center\"><a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/Screen-Shot-2015-10-21-at-10.56.14-AM.png\"><img decoding=\"async\" loading=\"lazy\" class=\"alignnone wp-image-3211 size-full\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/Screen-Shot-2015-10-21-at-10.56.14-AM.png\" alt=\"Screen Shot 2015-10-21 at 10.56.14 AM\" width=\"1202\" height=\"337\" \/><\/a><\/p>\n<p style=\"text-align: center\">Fig 3) Sources of Hydrogen Production House of Quality<\/p>\n<\/p><\/div>\n<\/section>\n<section id=\"builder-section-1443126913965\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Design Alternatives<\/h2>\n<\/header>\n<p><strong>Option One:<\/strong><\/p>\n<p class=\"p1\"><span class=\"s1\">Electrolysis: Proton H6<\/span><\/p>\n<ul>\n<li class=\"p1\"><span class=\"s1\">Output Amount: 12.94 kg\/day<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Pressure: 218 psig<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Purity: 99.9998%<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Power Draw: 6 kWhr\/m^3<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Connectors: 3\/8&#8243; Stainless Steel Compression Tube Outlet<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; Stainless Steel Water In<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; drain brass<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Volume: 179.29 ft^3<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Weight: 1700 lbs<\/span><\/li>\n<\/ul>\n<p>Additional H6 Info <a href=\"http:\/\/protononsite.com\/products\/h2-h4-h6\/#tab-documentation\">here<\/a><\/p>\n<p class=\"p1\"><strong><img decoding=\"async\" loading=\"lazy\" class=\"product-main-image aligncenter\" src=\"http:\/\/protononsite.com\/img\/products\/cropped\/413hogen_h_300dpi.jpg\" alt=\"\" width=\"212\" height=\"236\" \/><\/strong><\/p>\n<p class=\"p1\" style=\"text-align: center\">Fig 4) H6 Proton Electrolyzer<\/p>\n<p class=\"p1\"><strong>Option Two:<\/strong><\/p>\n<p class=\"p1\"><span class=\"s1\">Electrolysis: Proton C30<\/span><\/p>\n<ul>\n<li class=\"p1\"><span class=\"s1\">Output Amount: 65 kg\/day<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Pressure: 435 psig<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Purity: 99.9998%<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Power Draw: 134.38 kW<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Connectors: 3\/8&#8243; Stainless Steel Compression Tube Outlet<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; Stainless Steel Water In<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; drain brass<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Volume: 179.29 ft^3<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Weight 1700 lbs<\/span><\/li>\n<\/ul>\n<p>Additional C30 Info <a href=\"http:\/\/protononsite.com\/products\/h2-h4-h6\/#tab-documentation\">here<\/a><\/p>\n<p><a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/C30.png\"><img decoding=\"async\" loading=\"lazy\" class=\"size-medium wp-image-3153 aligncenter\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/C30-396x193.png\" alt=\"C30\" width=\"396\" height=\"193\" \/><\/a><\/p>\n<p style=\"text-align: center\">Fig 5) C30 Electrolyzer<\/p>\n<p><strong>Option Three:<\/strong><\/p>\n<p>Electrolysis:<strong>\u00a0<\/strong>HySTAT60<\/p>\n<ul>\n<li>24 to 60Nm<sup>3<\/sup>\/h (52 to 130 kg\/24hr)<\/li>\n<li>99,998% (99,999% as option)<\/li>\n<li>Process: 3.22m x 1.81m x 2.53m<br \/>\nControl Cabinet: 1.0m x 0.5m x 2m<br \/>\nPower Rack (2X): 0.9m x0.9m x 2.3m<\/li>\n<li>4.9 kWh\/Nm<sup>3<\/sup> at full load<\/li>\n<\/ul>\n<p>Additional HySTAT60 info <a href=\"http:\/\/www.hydrogenics.com\/hydrogen-products-solutions\/industrial-hydrogen-generators-by-electrolysis\/indoor-installation\/hystat-trade-60\/\">here<\/a><\/p>\n<p><a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/HySTAT60.png\"><img decoding=\"async\" loading=\"lazy\" class=\"wp-image-3011 aligncenter\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/HySTAT60.png\" alt=\"HySTAT60\" width=\"315\" height=\"414\" \/><\/a><\/p>\n<p style=\"text-align: center\">Fig 6) HySTAT60\u00a0Electrolyzer<\/p>\n<\/p><\/div>\n<\/section>\n<section id=\"builder-section-1443137533746\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Our Recommendation<\/h2>\n<\/header>\n<p><strong>After much research and the use of our House of Quality, we have determined that the Proton H6 will be our choice in hydrogen separation.\u00a0<\/strong><\/p>\n<p class=\"p1\"><span class=\"s1\">Electrolysis: Proton H6<\/span><\/p>\n<ul>\n<li class=\"p1\"><span class=\"s1\">Output Amount: 12.94 kg\/day<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Pressure: 218 psig<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Output Purity: 99.9998%<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Power Draw: 6 kWhr\/m^3<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Connectors: 3\/8&#8243; Stainless Steel Compression Tube Outlet<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; Stainless Steel Water In<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">1\/2&#8243; drain brass<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Volume: 179.29 ft^3<\/span><\/li>\n<li class=\"p1\"><span class=\"s1\">Weight: 1700 lbs<\/span><\/li>\n<\/ul><\/div>\n<\/section>\n<section id=\"builder-section-1447648424168\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>Economics<\/h2>\n<\/header>\n<p><strong>Initial and compounding cost estimates<\/strong><\/p>\n<ol>\n<li>The estimated cost for our subsystem will be around $90,000.<\/li>\n<li>Maintenance for the system will cost of $4,400 annually.<\/li>\n<li>Annual Operating Cost is $6,858<\/li>\n<li>The total amount of money that needs to be set aside now\u00a0to cover these costs for the next ten years at a 6% interest rate is\u00a0\u00a0$4212.40 \u2013 $8424.80<\/li>\n<li>Estimated cost of payoff time is around $161,176<\/li>\n<li>Money Set aside for 10 years is around $168,035<\/li>\n<\/ol>\n<p><strong>Depreciation and Book Value for 10 Years<\/strong><\/p>\n<p>H6 Hydrogen Generator<\/p>\n<p>Cost: $214,847.00<\/p>\n<p>Depreciation: $200,881.95<\/p>\n<p>Book Value: $123,153.53<\/p>\n<\/p><\/div>\n<\/section>\n<section id=\"builder-section-1443207575408\" class=\"row single gutter pad-top\">\n<div class=\"column one \">\n<header>\n<h2>What&#8217;s Next<\/h2>\n<\/header>\n<ul>\n<li>Compile all avenues for purchasing product<\/li>\n<li>We will continue to update you with new leaps in research and production<\/li>\n<\/ul><\/div>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p> <\/p>\n<h2>Our Team<\/h2>\n<p style=\"text-align: center\">\u00a0<a href=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/IMG_20151016_1358532.jpg\"><img decoding=\"async\" loading=\"lazy\" class=\"alignnone wp-image-3214 size-full\" src=\"https:\/\/hydrogen.wsu.edu\/wp-content\/uploads\/sites\/44\/2015\/09\/IMG_20151016_1358532.jpg\" alt=\"IMG_20151016_135853\" width=\"3645\" height=\"1122\" \/><\/a><\/p>\n<p style=\"text-align: center\">Hello! We are the WSU H2-Refuel Hydrogen Source Team.<br \/> &#8230; <a href=\"https:\/\/hub.wsu.edu\/ise\/design\/hydrogen-source\/\" class=\"more-link\"><span class=\"more-default\">&raquo; More &#8230;<\/span><\/a><\/p>\n","protected":false},"author":323,"featured_media":0,"parent":2908,"menu_order":5,"comment_status":"closed","ping_status":"closed","template":"template-builder.php","meta":{"_wsuwp_accessibility_report":[]},"wsuwp_university_location":[],"wsuwp_university_org":[],"_links":{"self":[{"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/pages\/1977"}],"collection":[{"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/users\/323"}],"replies":[{"embeddable":true,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/comments?post=1977"}],"version-history":[{"count":1,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/pages\/1977\/revisions"}],"predecessor-version":[{"id":2945,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/pages\/1977\/revisions\/2945"}],"up":[{"embeddable":true,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/pages\/2908"}],"wp:attachment":[{"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/media?parent=1977"}],"wp:term":[{"taxonomy":"wsuwp_university_location","embeddable":true,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/wsuwp_university_location?post=1977"},{"taxonomy":"wsuwp_university_org","embeddable":true,"href":"https:\/\/hub.wsu.edu\/ise\/wp-json\/wp\/v2\/wsuwp_university_org?post=1977"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}